Environmental Science & Engineering - www.esemag.com - January 2006
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Iron and manganese removal systems installed at two provincial parks

By Ahron Nahmias,P.Eng

Emily Provincial Park filtration system utilizes two parallel trains (Macrolite media and activated carbon filters), with 18-50 GPM per train at 60-100 PSI.
In order to meet the current drinking water regulation (Regulation 170/03) for a groundwater source under the direct influence of surface water, some of the provincial parks in Ontario were required to upgrade their drinking water purification plants.

Responding to this challenge, Metcon conducted pilot studies at two sites, specifically addressing the need for iron and manganese removal systems with an effective filtration system. The goal was to bring iron and manganese levels below the MOE’s aesthetic objective guidelines in a cost effective manner without adding any special iron removal filters for the job.

Pilot studies were conducted at Emily Provincial Park and Long Point Provincial Park for testing the efficiency of Macrolite media for iron and manganese removal after oxidation. Sodium hypochlorite, which is also an oxidant as well as the most common disinfectant, was used to study oxidation and subsequent filtration of iron and manganese by the filter media. Manganese behavior in well water varies and sometimes it is oxidized easily by NaOCl only; however at times it may require a stronger oxidant like potassium permanganate (KMnO4) or hydrogen peroxide (H2O2) to achieve desired levels of oxidation.

The pilot system installed at the sites included 40/60 mesh Macrolite ceramic media filters (one working and one standby) for turbidity, iron and manganese removal. This was followed by a 12/40 mesh activated carbon media filter to control trihalomethanes (THM), taste and odour issues. The pilot system also included chemical feed systems for polymer coagulant, NaOCl and KMnO4 feed, upflow contact tanks, and a bench scale analyzer for on-site measurement of treated water quality parameters.

The system operated for a week with an average run time of 6 hours per day and treated water parameters including turbidity, pH, free chlorine, total chlorine, iron and manganese levels were tested and recorded every 2 hours. It was run at various oxidant dosing levels in order to determine the optimized treatment strategy.

Results showed turbidity levels in treated water of 0.0 NTU consistently during the whole operation. 100% turbidity removal was achieved with the aid of on-line polymer coagulant dosing. Iron was easily oxidized by NaOCl only and efficiently removed by the Macrolite media filter bed, allowing for treated water iron levels recorded in the range of 0.00 to 0.02 mg/l. Manganese removal could not be achieved down to the desired level using only NaOCl as the oxidizing agent. However a combination of 3 mg/l of NaOCl feed and 0.14 mg/l of KMnO4 feed yielded treated water with a manganese level of 0.024 mg/l. No THM formation was observed during the whole process.

Treated water samples were sent to SGS Lakefield for testing and found consistent with on-site testing.

The studies established the efficiency of Macrolite media for iron and manganese removal from well water. Superior turbidity, iron and manganese removal rates were successfully achieved by only using approximately 12 minutes of contact time for oxidation. Based on the study data, full-scale systems were installed at both sites to meet the desired removal levels of iron, manganese, turbidity and pathogens. With minimal monitoring and human intervention, both systems continue to supply safe drinking water that meet and exceed regulations.


Ahron Nahmias is with Metcon Sales and Engineering Limited
Contact: ahronn@metconeng.com


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