Environmental Science & Engineering - www.esemag.com - March 2004
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Go with the flow to clean up land

A UK-based geotechnical contractor is developing a way of cleaning potentially hazardous ground contamination. The process involves placing a permeable reactive barrier in the flow path of contaminated groundwater.
A team of engineers and academics is piloting an innovative but simple process that exploits the natural flow of groundwater to clean up contaminated land.

The most common approach to contaminated land remediation in the United Kingdom is “dig and dump” - removing potentially hazardous material to a controlled landfill site. Equally well-established is the practice of isolating a pollutant source by enclosing it in impermeable slurry walls, made from a mix of clay and grout, with a compacted clay capping layer.

Although the containment option is arguably more sustainable than removing contaminated material, it can be perceived as a “toxic timebomb”.

UK-based geotechnical contractor Keller Ground Engineering is one of a handful of European firms developing a technique that promises to provide an inexpensive, safe and highly effective way of cleaning potentially hazardous ground contamination.

The process involves placing a permeable reactive barrier (PRB) in the flow path of contaminated groundwater. The PRB is so called because it contains reactive materials that immobilize and/or neutralize the pollutants as they pass through it. The type of materials used depends on the nature of the contaminant.

“A key difference between PRBs and other in situ groundwater remediation techniques,” according to Keller’s business development director Martyn Singleton, “is that the contamination moves through the treatment zone.” With most other techniques it is the other way round, which makes it difficult to ensure that all the contamination has come into contact with the treatment reagent.

The process can be achieved by one of two approaches. With the funnel and gate technique, impermeable walls direct contaminated groundwater to gates containing a reactive material. Continuous PRBs consist of trenches, filled usually with gravel and a reagent, positioned within the flow of groundwater.

Keller favours the former for its greater versatility. “The gates are usually prefabricated steel boxes encapsulated within an impermeable trench constructed in the ground,” says Keller engineer Dr. Denis Greene. “This allows for removal or exchange of the reactive material within the gate.”

Keller’s first PRB contract at Monkstown in Northern Ireland cost the client £750,000, about £250,000 less than conventional dig and dump. A more recent project at Portadown cost £500,000, saving the client an estimated £1.6 million.

Costs are also favourable when compared with a perimeter slurry wall and capping system, Keller says, because the length of barrier required to funnel or intersect the contamination plume is far less than that required to enclose a pollutant.

The company readily admits that the use of PRBs is technically challenging, from the conceptual design of treatment through to site installation. With this in mind, it is working closely with scientists at Queen’s University Belfast to identify pollutants that can be treated using PRB technology, and to match them to the most appropriate neutralizing reagents.

“High-quality site characterization is especially important for implementing a PRB correctly,” says Dr. Greene. “It is essential to determine the spread and concentrations of contaminants in the groundwater and to establish the local geology and hydrogeology (pattern of groundwater flow).”

It is normally necessary to carry out a trial to confirm the degradation of the contamination and the calculated half-life - the time needed to half the contamination concentration - and the volume of reactive material required.

Typical design may be based on 10 to 30 years of treatment before the source has attenuated. Keller’s experience so far suggests that because this is a passive system, operating costs and maintenance are relatively low.

The UK’s Environment Agency (EA) recently produced new guidelines on the use of PRBs, and the technique now falls within its remit to “promote and encourage the effective use of sustainable remediation technologies”. Such is the EA’s enthusiasm for PRBs that it is even relaxing the licensing requirements for operators wanting to implement a PRB scheme.

For these reasons, the approach looks set to become widely adopted in the UK and beyond.
Contact, Dr. Alan Bell, e-mail: alan.bell@keller-ge.co.uk.

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