Environmental Science & Engineering - www.esemag.com - September 2003
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Many municipalities tap into the benefits of EDR water treatment


Diagram of a hollow fibre UF membrane.

No one wants to drink radium. Or nitrates. Or arsenic. Methods like electrodialysis reversal (EDR), provide treatment options.

Just ask the citizens of Washington, Iowa. In 1979, Washington was notified by the Iowa Department of Natural Resources that the city was in violation of the radium standard for drinking water. Even then, radium was recognized as a carcinogen. The city evaluated a number of options for improving the water quality and removing the radium from the water. They decided on implementing the process known as EDR, a relatively new variation on the electrodialysis process which had been commercialized by Ionics. The technology was incorporated in the 1950s.

Today, there are many other examples of cities, towns and municipal organizations that have found EDR demineralization to be an economical, high-performance way to transform unusable water into safe drinking water. Major applications for EDR include: the purification of drinking water from brackish sources; demineralization of water from industrial processes; reuse of municipal effluent; and reduction of mineral concentrations in wastewater.

A self-cleaning process
EDR is a variation on the electrodialysis process, in that it uses electrode polarity reversal to automatically clean membrane surfaces. The electrodialysis process uses a driving force of direct current (DC) power to transfer ionic species from the source waterfeed water through cation (positively charged ions) and anion (negatively charged ions) transfer membranes to a concentrate wastewater stream, creating a more dilute stream.

EDR works the same way, except that the polarity of the DC power is reversed two to four times per hour. When the polarity is reversed, the sourcewater dilute and concentrate compartments are also reversed. The alternating exposure of membrane surfaces to the product dilute and brine concentrate streams provides a selfcleaning capability that enables purification and recovery of up to 94% of the feed water.

There are currently a number of alternatives to the EDR technology for treating and reducing contaminants in drinking water and feed water. Probably the most well-known of these is reverse osmosis (RO). Both EDR and reverse osmosis use semipermeable membranes to filter out dissolved ions from water. But where RO uses the application of pressure to overtake osmotic pressure and shift the water flow force water through the membranes, EDR uses voltage potential and polarity reversal to flush out the unwanted particles to force contaminants through the membranes.

An evolving technology
Over the last 10 to 15 years, numerous advances in membrane and system technology are claimed for EDR, both in terms of performance and cost effectiveness. Improved membrane technology now allows for one-step machine manufacture of ion exchange membranes, reducing costs and lowering membrane resistivity. And new high performance spacers (placed between the membranes) allow better transport of contaminants like nitrates, speeding the process, reducing the number of membrane stacks required and shrinking costs.

Major improvements to EDR system design are claimed in the form of the next generation Ionics EDR 2020® system. This new design streamlines the process flow with simpler hydraulics and standardized components, substantially lowering the capital and operating costs of EDR demineralization. It features the new spacer technology, as well as a more compact design that is said to be easy to install in an array of configurations.

The new generation EDR systems, with up to half as many membrane stacks, standardized components and simpler hydraulics, have demonstrated a 30% reduction in capital cost savings.
Contact Ionics, Incorporated: Francine Bernitz, e-mail: fbernitz@ionics.com or Antonia von Gottberg, e-mail: avongottberg@ionics.com.

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